Article ID Journal Published Year Pages File Type
5380271 Chemical Physics Letters 2014 5 Pages PDF
Abstract

- Chemiluminescence of γ-irradiated polytetrafluoroethylene powder was measured.
- Series first-order reactions were assumed to explain the time evolution.
- Rate constants for the reactions were determined by least-squares fitting.
- Activation energy was derived from the temperature dependence of rate constants.
- Dissociation energy of the OO bond was evaluated by the DFT calculation.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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