Article ID Journal Published Year Pages File Type
5380291 Chemical Physics Letters 2014 6 Pages PDF
Abstract

- Relaxation pathways of the LMCT-excited Cu(II) Cl-complexes in CH3CN were revealed.
- Combination of the steady-state photolysis and ultrafast spectroscopy was used.
- Major part of the LMCT-excited complexes relaxes to ground state parent complex.
- Minor fraction of the LMCT-excited complexes dissociates into photoproducts.
- [CuIICln]2−n photodissociate into [CuIICln−1]3−n + Cl− and [CuICln−1]2−n + Cl.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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