Article ID Journal Published Year Pages File Type
5381602 Chemical Physics Letters 2013 5 Pages PDF
Abstract

- Spin probe TEMPO dynamics in 1,2- and 1,4 poly(butadiene)s measured by ESR.
- Ortho-positronium (o-Ps) annihilation studies performed by PALS.
- The opposite T50G/Tg < 1 and T50G/Tg > 1 ratios found.
- Almost constant o-Ps lifetime at T50G transition independently of physical state.
- Free volume fluctuation as a controlling factor of T50G transition.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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