Article ID Journal Published Year Pages File Type
5381603 Chemical Physics Letters 2013 23 Pages PDF
Abstract

- The equilibrium liquid-liquid transition of triphenyl phosphite was detected by DSC.
- The temperature of the LLT from glacial phase to supercooled liquid is 241.7 K.
- LLT enthalpy and entropy are 12.0 kJ mol−1 and 49.5 J K−1 mol−1, respectively.
- The glacial phase has much smaller residual entropy than the glassy liquid.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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