Article ID Journal Published Year Pages File Type
5381959 Chemical Physics Letters 2013 5 Pages PDF
Abstract

- The existence of both physical and chemical interactions between [aEMMIM][BF4] and CO2 was verified.
- A method to estimate the ratio of physical and chemical interactions between [aEMMIM][BF4] and CO2 based on NMR spectra was proposed.
- The chemical interaction mechanism of [aEMMIM][BF4] and CO2 was proved to 1:1 stoichiometry by NMR and DFT calculations.
- Tethering high sterically substitute group at IL helps to obtain an equimolar CO2 absorption.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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