| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5382043 | Chemical Physics Letters | 2013 | 5 Pages |
Abstract
- Stilbene isomerization rates k(λexc) in solution weakly depend on λexc.
- The k(λexc) dependence in solution cannot be reproduced with current theories.
- Experimental results can be explained by adding a solvent contribution to the rate.
- The rate in solution can be the sum of intramolecular and solvent contribution.
- A particular activation mechanism by solvent collisions is discussed.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
S.A. Kovalenko, A.L. Dobryakov,