| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5382304 | Chemical Physics Letters | 2013 | 6 Pages |
Abstract
The strong enhancement of H-atom UV-photogeneration is revealed in van der Waals complexes of unsaturated hydrocarbons RH (RHethylene C2H4, propylene C3H6, butadiene C4H6, butene-2 C4H8) with oxygen RH-O2 as compared with the 'free' RH molecules. The results obtained indicate enhancement of H atom yield to be due to one-quantum photoprocess 1RH-3O2 + hν â 3RHâ + 3O2(1O2) providing triplet RH molecules with excitation level sufficient for dissociation.
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Authors
Alexey V. Baklanov, Alexandr S. Bogomolov, Leonid M. Chikishev, Georgii A. Bogdanchikov, Sergei A. Kochubei,