Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5382344 | Chemical Physics Letters | 2012 | 6 Pages |
Abstract
⺠The rupture characteristics of organometallic complexes is tunable via the ligand. ⺠Electronic effects nontrivially impact rupture characteristics and materials design. ⺠The mechanism for bond rupture was found to be of closed-shell character. ⺠The initial response to tension is dominated by symmetric coordinative-bond-stretching. ⺠Rupture is concurrent with a sudden significant rearrangement of the ligands.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
B. Christopher Rinderspacher, Jan W. Andzelm, Robert H. Lambeth,