Article ID Journal Published Year Pages File Type
5382425 Chemical Physics Letters 2012 5 Pages PDF
Abstract
► Time-resolved infrared spectroscopy is used to study photo-induced NO linkage isomerisation. ► The vibronic coupling in the excited state allows for the ultrafast NO rotation of 90° within 300 fs. ► The vibrational-rotational relaxation leads then to the metastable side-on NO configuration. ► The latter state has a lifetime of about 300 ns at room temperature.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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