Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5382425 | Chemical Physics Letters | 2012 | 5 Pages |
Abstract
⺠Time-resolved infrared spectroscopy is used to study photo-induced NO linkage isomerisation. ⺠The vibronic coupling in the excited state allows for the ultrafast NO rotation of 90° within 300 fs. ⺠The vibrational-rotational relaxation leads then to the metastable side-on NO configuration. ⺠The latter state has a lifetime of about 300 ns at room temperature.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Geoffrey Gallé, Matthieu Nicoul, Theo Woike, Dominik Schaniel, Eric Freysz,