Article ID Journal Published Year Pages File Type
5382562 Chemical Physics Letters 2013 7 Pages PDF
Abstract
► We show the vib-rotational Raman spectra of chlorine in doped 3He and 4He clusters. ► We apply the Full-Configuration-Interaction Nuclear-Orbital approach to probe Coriolis effects for the first time. ► The spectra in 4He are unaffected by Coriolis couplings. ► The spectra in 3He are much more complex, highlighting a strong temperature-dependence. ► Spin-dependent Coriolis couplings play a key role in 3He.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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