Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5382562 | Chemical Physics Letters | 2013 | 7 Pages |
Abstract
⺠We show the vib-rotational Raman spectra of chlorine in doped 3He and 4He clusters. ⺠We apply the Full-Configuration-Interaction Nuclear-Orbital approach to probe Coriolis effects for the first time. ⺠The spectra in 4He are unaffected by Coriolis couplings. ⺠The spectra in 3He are much more complex, highlighting a strong temperature-dependence. ⺠Spin-dependent Coriolis couplings play a key role in 3He.
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Authors
Néstor F. Aguirre, Pablo Villarreal, Gerardo Delgado-Barrio, Alexander O. Mitrushchenkov, MarÃa Pilar de Lara-Castells,