| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5382700 | Chemical Physics Letters | 2012 | 6 Pages |
Abstract
⺠The Al + HCN reaction is carried out at low temperature in a helium nanodroplet. ⺠Barrierless association leads to a bent HCNAl species with a 130° HCN bond angle. ⺠A Rotationally resolved CH stretch band for bent HCNAl is found red shifted 619 cmâ1 from free HCN. ⺠Natural Bond Orbital analysis reveals substantial Al p-electron delocalization within HCNAl.
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Authors
Tao Liang, Gary E. Douberly,