Article ID Journal Published Year Pages File Type
5382728 Chemical Physics Letters 2012 5 Pages PDF
Abstract
► Thermal decomposition of dimethylsulfoxide on TiO2 occurs at a temperature >100 °C. ► With dissociation of the C-S and C-H bonds, CH3O, HCOO and S are formed. ► O2 has negligible effect on the thermal reaction, but transforming the S to SO4. ► DMSO(a) photodegradation in a vacuum generates CH3O, HCOO and CH3S. ► The presence of O2 further oxidizes the CH3S into CH3SO3.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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