| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5382816 | Chemical Physics Letters | 2012 | 6 Pages |
Abstract
⺠Explicitly correlated wave functions are employed to study atomic transitions. ⺠Different correlation mechanisms are analyzed for dipole transitions to the ground state for the atoms Li to Ar. ⺠The correlation factor improves the excitation energies. ⺠The correlation factor does not improve significantly transition probabilities, oscillator strength and line strengths. ⺠Configuration mixing is more important than the Jastrow factor for the transition probabilities.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
E. BuendÃa, F.J. Gálvez, P. Maldonado, A. Sarsa,