Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5382828 | Chemical Physics Letters | 2012 | 7 Pages |
Abstract
⺠Reactivity of gold(III) complexes are modeled. ⺠Direct substitution reaction and ring-opening are addressed. ⺠The kinetics follows the order: SCNâ > N3â > H2O and the thermodynamics: N3â > SCNâ > H2O. ⺠Ring-opening side reaction is kinetically important for SCNâ and N3â.
Related Topics
Physical Sciences and Engineering
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Physical and Theoretical Chemistry
Authors
Hélio F. Dos Santos, Diego Paschoal, Jaroslav V. Burda,