Article ID Journal Published Year Pages File Type
5382828 Chemical Physics Letters 2012 7 Pages PDF
Abstract
► Reactivity of gold(III) complexes are modeled. ► Direct substitution reaction and ring-opening are addressed. ► The kinetics follows the order: SCN− > N3− > H2O and the thermodynamics: N3− > SCN− > H2O. ► Ring-opening side reaction is kinetically important for SCN− and N3−.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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