Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5382840 | Chemical Physics Letters | 2012 | 6 Pages |
Abstract
⺠Femtosecond time resolved vibrational SFG has been used for the first time to probe interfacial chemical reactions. ⺠We obtained the ultrafast dynamics of electron transfer at a water/DMA monolayer interface. ⺠The forward electron transfer at the interface faster than electron transfer in bulk DMA. ⺠The faster rate is attributed to a lower reorganization free energy at the interface.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Yi Rao, Man Xu, Steffen Jockusch, Nicholas J. Turro, Kenneth B. Eisenthal,