| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5382878 | Chemical Physics Letters | 2012 | 7 Pages |
Abstract
⺠A peptide model is used to study non-specific solvent effects on chemical shifts. ⺠Chemical shifts are highly sensitive to dielectric constant, ε, of the medium. ⺠The dependence can be approximated as an effect of the solvent reaction field. ⺠Small deviation of ε at the low-value region can induce large chemical shift changes. ⺠Averaged backbone chemical shifts suggest low effective ε for protein interior.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Aleksandr B. Sahakyan,