| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5383373 | Chemical Physics Letters | 2012 | 5 Pages |
Abstract
⺠Interaction of flexible and rigid crown ether towards K+ ion has been investigated. ⺠Thermodynamic parameters have been calculated applying van't Hoff equation. ⺠Entropy decreased slightly in case of formation of flexible crown ether K+ complex. ⺠Entropy increased in case of formation of rigid crown ether K+ complex. ⺠Molecular vibrations are responsible for the entropy changes at molecular level.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Yin Li, Péter Huszthy, Sándor Kunsági-Máté,