| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5383374 | Chemical Physics Letters | 2012 | 6 Pages |
Abstract
⺠Crystal structure of ScB12 suggests the possible existence of closo B24H242-. ⺠Shrinkage plus pseudorotation of B24 truncated octahedron in ScB12 relates crystal and molecular structure. ⺠Exohedral and endohedral [Scâ¯B24H24]+ complexes are characterized with quantum-chemical computations. ⺠The B24H242- optimized molecular structure exists as a building block in the NaZn13-type structure, among others.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
![Merging boron solid state and molecular chemistry: Energy landscapes in the exo/endo closo-borane complex Sc[B24H24]+](/preview/png/5383374.png "First Page Preview: Merging boron solid state and molecular chemistry: Energy landscapes in the exo/endo closo-borane complex Sc[B24H24]+")
Authors
Josep M. Oliva, Ángel Vegas,