Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5383631 | Chemical Physics Letters | 2012 | 6 Pages |
Abstract
⺠LIF spectroscopy and photophysics of 7-azaindoleâ¯2-pyrrolidinone complex. ⺠The vibronic bands in the fluorescence excitation spectrum show puckering doublets. ⺠Puckering barrier is predicted â¼260 cmâ1 and zero-point splitting 10 cmâ1. ⺠Complex emits tautomer fluorescence in hydrocarbon solution but UV emission in jet. ⺠High barrier is suggested for inhibition of tautomerization in isolated complex.
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Authors
Moitrayee Mukherjee, Shreetama Karmakar, Tapas Chakraborty,