Article ID Journal Published Year Pages File Type
5383631 Chemical Physics Letters 2012 6 Pages PDF
Abstract
► LIF spectroscopy and photophysics of 7-azaindole⋯2-pyrrolidinone complex. ► The vibronic bands in the fluorescence excitation spectrum show puckering doublets. ► Puckering barrier is predicted ∼260 cm−1 and zero-point splitting 10 cm−1. ► Complex emits tautomer fluorescence in hydrocarbon solution but UV emission in jet. ► High barrier is suggested for inhibition of tautomerization in isolated complex.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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