| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5383659 | Chemical Physics Letters | 2011 | 9 Pages |
Abstract
⺠X-ray absorption spectra of the aqueous carbon cycle measured using liquid microjets. ⺠Carbonate (pH = 12), bicarbonate (pH = 8.5), and carbonic acid/CO2 (pH = 3) were probed. ⺠Electronic and dynamical simulations reveal the origins of clear spectral differences. ⺠Defining factors are molecular configuration, bond lengths, and hydration strength. ⺠Vibronic peaks in CO2 spectra are particularly sensitive to aqueous solvation.
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Authors
Alice H. England, Andrew M. Duffin, Craig P. Schwartz, Janel S. Uejio, David Prendergast, Richard J. Saykally,