| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5383756 | Chemical Physics Letters | 2011 | 11 Pages |
Abstract
⺠Recorded nascent rotational and vibrational spectra of molecules spontaneously evaporating. ⺠Rotations are cooled significantly more than the lowest-energy vibrational modes. ⺠Rotational energy distributions are Boltzmann, T(rot) = 200-230 K. ⺠Vibrational analysis indicates liquid surface temperature of 260-270 K. ⺠During phase transition, equivalent of 150-260 hard sphere collisions occur.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Olivia J. Maselli, Jason R. Gascooke, Warren D. Lawrance, Mark A. Buntine,