Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5383836 | Chemical Physics Letters | 2011 | 7 Pages |
Abstract
⺠Experimental comparison between the Butler-Volmer and Marcus-Hush models is performed. ⺠The reductions of 2-methyl-2-nitropropane and Eu(III) at Hg microelectrodes are considered. ⺠Cyclic voltammetry reveals significant differences between models. ⺠Butler-Volmer adequately fits experimental data with consistent kinetic parameters. ⺠Marcus-Hush does not always enable satisfactory fitting of experimental voltammetry.
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Authors
Martin C. Henstridge, Yijun Wang, Juan G. Limon-Petersen, Eduardo Laborda, Richard G. Compton,