Article ID Journal Published Year Pages File Type
5383836 Chemical Physics Letters 2011 7 Pages PDF
Abstract
► Experimental comparison between the Butler-Volmer and Marcus-Hush models is performed. ► The reductions of 2-methyl-2-nitropropane and Eu(III) at Hg microelectrodes are considered. ► Cyclic voltammetry reveals significant differences between models. ► Butler-Volmer adequately fits experimental data with consistent kinetic parameters. ► Marcus-Hush does not always enable satisfactory fitting of experimental voltammetry.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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