Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5383865 | Chemical Physics Letters | 2011 | 5 Pages |
Abstract
⺠The electronic structure of HfF5- and WF5- is computed using ab initio methods. ⺠Hafnium fluorides are much more stable than the corresponding tungsten fluorides. ⺠The detachment energy is 8.8 eV for HfF5- and is only 3.9 eV for WF5-. ⺠It is possible to photodetach WF5- while leaving HfF5- unaffected. ⺠Photodetachment can be used to suppress interfering 182W in the detection of 182Hf.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Hongshan Chen, Pontus Andersson, Anton O. Lindahl, Dag Hanstorp,