Article ID Journal Published Year Pages File Type
5383865 Chemical Physics Letters 2011 5 Pages PDF
Abstract
► The electronic structure of HfF5- and WF5- is computed using ab initio methods. ► Hafnium fluorides are much more stable than the corresponding tungsten fluorides. ► The detachment energy is 8.8 eV for HfF5- and is only 3.9 eV for WF5-. ► It is possible to photodetach WF5- while leaving HfF5- unaffected. ► Photodetachment can be used to suppress interfering 182W in the detection of 182Hf.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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