Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5383873 | Chemical Physics Letters | 2011 | 6 Pages |
Abstract
⺠We have investigated the pressure-induced conformational changes of imidazolium-based RTILs. ⺠The trans conformer of the CNCC angle of the [emim]+ cation becomes predominant at high pressure. ⺠The conformational change of the CNCC angle of the [bmim]+ cation is independent of pressure. ⺠The gauche-trans conformer for the butyl cation of the [bmim]+ cation is predominant at high pressure. ⺠The [emim]+ and [bmim]+ cations cause the respective conformational preferences at high pressures.
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Authors
Takahiro Takekiyo, Yusuke Imai, Naohiro Hatano, Hiroshi Abe, Yukihiro Yoshimura,