Article ID Journal Published Year Pages File Type
5384017 Chemical Physics Letters 2011 6 Pages PDF
Abstract
► Calculated dynamic Stokes' shifts for these ILs range between ∼2300 and 3700 cm−1. ► Suggests a total domination (∼75-85%) of probe-IL dipolar interaction. ► Ion-size crucial for the ion-dipole interaction contribution to the total shift. ► Predicts a presence of sub-50 fs component with substantial amplitude. ► Ultrafast response originates from the collective orientational relaxation.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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