Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5384073 | Chemical Physics Letters | 2011 | 4 Pages |
Abstract
⺠Radical generated by homolysis of the axial metal-ligand bond in a macrocycle. ⺠Electron delocalization through the conjugated ring contributes to the stability. ⺠Descriptors about the distribution of the unpaired electron in the radical. ⺠Competition of electron doping sites: metal-centered versus macrocycle-centered. ⺠Redox chemistry and electron transfer are affected by planarity.
Related Topics
Physical Sciences and Engineering
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Physical and Theoretical Chemistry
Authors
Yang Yang,