Article ID Journal Published Year Pages File Type
5384073 Chemical Physics Letters 2011 4 Pages PDF
Abstract
► Radical generated by homolysis of the axial metal-ligand bond in a macrocycle. ► Electron delocalization through the conjugated ring contributes to the stability. ► Descriptors about the distribution of the unpaired electron in the radical. ► Competition of electron doping sites: metal-centered versus macrocycle-centered. ► Redox chemistry and electron transfer are affected by planarity.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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