Article ID Journal Published Year Pages File Type
5384088 Chemical Physics Letters 2011 6 Pages PDF
Abstract
► A Ru-complex bearing cooperative PNP ligands shows unprecedented catalysis in the reversible dehydrogenation of BH3NH3. ► The barrier for H2 formation from NH3BH3 is strongly reduced by Ru-complex, and one additional H2 is produced. ► The Ru-catalyst can be used for H2 release from chemical hydrogen storage materials such as hydrazine and ammonia alane.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Hydrogen release from ammonia borane and derivatives in the presence of a ruthenium complex incorporating cooperative PNP ligands
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