| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5384164 | Chemical Physics Letters | 2011 | 5 Pages |
Abstract
⺠Experimental comparison between Butler-Volmer and Marcus-Hush models is performed. ⺠The reduction of 2-methyl-2-nitropropane at mercury microelectrodes is considered. ⺠Reverse Scan Square Wave Voltammetry reveals significant differences between models. ⺠Butler-Volmer adequately fits experimental data with consistent kinetic parameters. ⺠Marcus-Hush does not enable satisfactory quantitative description of the redox system.
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Authors
Eduardo Laborda, Yijun Wang, Martin C. Henstridge, Francisco MartÃnez-Ortiz, Angela Molina, Richard G. Compton,