Article ID Journal Published Year Pages File Type
5384431 Chemical Physics Letters 2011 7 Pages PDF
Abstract
► The coinage metal encapsulated group 14 cationic clusters X10M+ with X = Ge, Sn, Pb and M = Cu, Ag, Au are magic cluster with high stability and aromaticity. ► The concept of doubly spherical aromaticity, based on the number of 2(N + 1)2 π and σ valence electrons, is proposed to account for the enhanced stability. ► Predictions are in good agreement with experiment for available X10Cu+ clusters.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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