Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5384506 | Chemical Physics Letters | 2011 | 6 Pages |
Abstract
⺠Mid-IR spectroscopy of enol and keto forms of acetylacetone in solid parahydrogen. ⺠Precise vibrational assignments based on anharmonic calculations. ⺠Higher keto/enol ratio in parahydrogen than in other matrices. ⺠UV induced tautomerization from enol to keto leading to samples containing only keto. ⺠Non-chelated enol forms are intermediates in the tautomerization process.
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Authors
Rolando R. Lozada-Garcia, Justinas Ceponkus, Wutharath Chin, Michèle Chevalier, Claudine Crépin,