| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5384517 | Chemical Physics Letters | 2011 | 6 Pages |
Abstract
⺠Oscillator strengths and Judd-Ofelt intensity parameters of LnBr3 are calculated with multi-reference spin-orbit CI method. ⺠Intensities of f-f hypersensitive transitions are dominated by the dynamic-coupling model. ⺠The intensities calculated with the dynamic-coupling model are overestimated due to the neglect of the polarization shielding effect. ⺠Ligand to metal charge transfer to an empty 4f orbital cannot be neglected especially in EuBr3.
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Authors
Miho Hatanaka, Satoshi Yabushita,