| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5384888 | Chemical Physics Letters | 2010 | 5 Pages |
Abstract
⺠The simulation reveals that the silver(I) acts as a structure breaker in aqueous solution indicated by its very low mean ligand residence time. ⺠The first hydration shell is composed of two different types of ligands at varying bond lengths. ⺠As in the case of hydrated gold(I) the second hydration shell is composed of an exceptionally large number of water molecules. ⺠Selection of configurations with a given coordination number (i.e. 5-, 6- and 7-coordinated species) enables a more detailed analysis of the hydrated, highlighting the problems associated to systems with rapidly exchanging ligands.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
C. Markus Blauth, Andreas B. Pribil, Bernhard R. Randolf, Bernd M. Rode, Thomas S. Hofer,