Article ID Journal Published Year Pages File Type
5384890 Chemical Physics Letters 2010 4 Pages PDF
Abstract
►Reaction mechanism of phosphate monoester hydrolysis. ►Free energy profile calculated at the DFT/COSMO level. ►Desolvation effects on the reaction mechanism. ►Stepwise dissociative mechanism preferred in low dielectric environments. ►Relevance for dramatic acceleration of phosphate hydrolysis.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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