Article ID Journal Published Year Pages File Type
5384897 Chemical Physics Letters 2010 7 Pages PDF
Abstract
► SDBS molecules can interact with quinone-hydrazone tautomer of anionic EBT molecule and stabilizes it, whereas SDS cannot. ► The nature of interaction between SDBS and EBT is charge transfer type. ► Electron rich SDBS acts as electron donor and electron deficient quinone-hydrazone tautomer of EBT acts as acceptor. ► The interaction between SDBS and EBT shifts tautomerisation of EBT to less stable quinone-hydrazone form at pH 7.0. In the absence of SDBS, this tautomerisation happens at pH 9.45.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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