Article ID Journal Published Year Pages File Type
5384917 Chemical Physics Letters 2010 4 Pages PDF
Abstract
► A new mechanism of non-FC distributions in free molecules is predicted. ► The mechanism is originated by coupling of valence and electronic transitions. ► The work of the mechanism is examined by considering C 1s shell ionization in CO. ► The distribution fv' differs substantially from the FC-distribution for v′>4. ► The mechanism is general and works in photoemission from various chemical compounds.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Authors
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