Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5385118 | Chemical Physics Letters | 2010 | 6 Pages |
Abstract
⺠The double layer and diffusion layer are decoupled for large electrodes. ⺠If this decoupling is accurate, the zero-field approximation applies. ⺠If kinetics are fast, the position of electron transfer does not affect the voltammetry.⺠If kinetics are slow, a fuller treatment is required due to 'Frumkin corrections'.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Edmund J.F. Dickinson, Richard G. Compton,