Article ID Journal Published Year Pages File Type
5385118 Chemical Physics Letters 2010 6 Pages PDF
Abstract
► The double layer and diffusion layer are decoupled for large electrodes. ► If this decoupling is accurate, the zero-field approximation applies. ► If kinetics are fast, the position of electron transfer does not affect the voltammetry.► If kinetics are slow, a fuller treatment is required due to 'Frumkin corrections'.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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