| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5385297 | Chemical Physics Letters | 2010 | 5 Pages |
Abstract
⺠An interesting reversal in the enthalpic behavior from endothermic to exothermic on increasing the carbon chain length attached to the imidazolium ring in the imidazolium-based ionic liquids. ⺠The excess partial molar enthalpy, HILE directly measured using isothermal titration calorimeter at 298.15 K for the interactions operating between cation and anion of four imidazolium ionic liquids with aqueous and various non-aqueous solvents. ⺠This reversal behavior analyzed in terms of hydrophobic and solvation effects.
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Authors
Gitanjali Rai, Anil Kumar,