| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5385483 | Chemical Physics Letters | 2010 | 4 Pages |
Abstract
The Gibbs energy cost of cavity creation and the Gibbs energy gain due to benzene-alkane attractive interactions depend on the chain-length of the n-alkane molecule; both these Gibbs energy contributions account for the difference in size between the solute and solvent molecules, disproving the need to correct the Ben-Naim standard transfer Gibbs energy values by a Flory-Huggins correction term.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Giuseppe Graziano,