| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5386077 | Chemical Physics Letters | 2010 | 7 Pages |
Abstract
⺠Rotations of both CO and ethylene oxide are hindered in Type I clathrate hydrates. ⺠Steric effects are responsible for hindering of CO rotations. ⺠The rotational hindering sharpens and intensifies the C-O stretch band. ⺠van der Waals interactions hinder ethylene oxide rotations. ⺠Neither guest-induced H-bonds nor L-defects are formed below 110 K.
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Authors
Lukasz Cwiklik, J. Paul Devlin,