Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5386689 | Chemical Physics Letters | 2009 | 5 Pages |
Abstract
The first band for n-type BGG is sensitive to temperature, while the second band is sensitive for p-type BGG. The change of Ba/Ga ratio, from which the carrier type is controlled in this system, modifies the positions of Ga residing at the larger (Ga-Ge)24 outer cage. This modification in the surrounding framework is responsible for the large differences observed in electronic properties of p- and n-BGGs in this clathrate family.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Jun Tang, Ryotaro Kumashiro, Jing Ju, Zhaofei Li, Marcos A. Avila, Kouichirou Suekuni, Toshiro Takabatake, Fangzhun Guo, Keisuke Kobayashi, Katsumi Tanigaki,