Article ID Journal Published Year Pages File Type
5386689 Chemical Physics Letters 2009 5 Pages PDF
Abstract
The first band for n-type BGG is sensitive to temperature, while the second band is sensitive for p-type BGG. The change of Ba/Ga ratio, from which the carrier type is controlled in this system, modifies the positions of Ga residing at the larger (Ga-Ge)24 outer cage. This modification in the surrounding framework is responsible for the large differences observed in electronic properties of p- and n-BGGs in this clathrate family.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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