| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5387818 | Chemical Physics Letters | 2008 | 4 Pages |
Abstract
Solvation effects in SN2-type oxidative addition of MeI to PtMe2(NH3)2 was theoretically investigated with RISM-SCF. Though the reaction may not occur in gas phase because of the high barrier due to dissociation of iodide anion from methyl group, the reaction easily occurs in nitromethane because the iodide anion is stabilized by nitromethane solvent.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Seigo Hayaki, Daisuke Yokogawa, Hirofumi Sato, Shigeyoshi Sakaki,