Article ID Journal Published Year Pages File Type
5387893 Chemical Physics Letters 2008 4 Pages PDF
Abstract
The very high reactivity of aminoalkyl radicals toward the halogen abstraction reaction is reported for the first time. Reaction rate constants with CCl4 and CBr4 are close to the diffusion limit: they are about 4-5 orders of magnitude higher than those previously determined for typical alkyl radicals.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Halogen abstraction reaction between aminoalkyl radicals and alkyl halides: Unusual high rate constants
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