| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5387949 | Chemical Physics Letters | 2008 | 8 Pages |
Abstract
Longitudinal static second hyperpolarizability (γ) of open-shell singlet radical dimer is found to be significantly enhanced as compared to that of monomer due to the field-induced intermolecular virtual charge transfer between both-end phenalenyl rings through the strong covalent interaction between the unpaired electrons of the cofacial phenalenyl rings.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Masayoshi Nakano, Akihito Takebe, Ryohei Kishi, Hitoshi Fukui, Takuya Minami, Kazuki Kubota, Hideaki Takahashi, Takashi Kubo, Kenji Kamada, Koji Ohta, Benoît Champagne, Edith Botek,