| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5388819 | Chemical Physics Letters | 2007 | 4 Pages |
Abstract
We report the orthoaxial and axial X-ray circular dichroism spectra of a homochiral single crystal of {Î-[Co(en)3]Cl3}2 · NaCl · 6H2O. We have extracted the absolute values of the electric quadrupole and electric dipole contributions to the intensity of the 1s â 3d transition and compare these to an ab initio calculation.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
![Orthoaxial single crystal X-ray circular and linear dichroism of the 1s â 3d transition of {Î-[Co(en)3]Cl3}2 · NaCl · 6H2O: Measurement of the absolute values of the quadrupole and dipole contributions to the intensity of a pre-edge transition](/preview/png/5388819.png "First Page Preview: Orthoaxial single crystal X-ray circular and linear dichroism of the 1s â 3d transition of {Î-[Co(en)3]Cl3}2 · NaCl · 6H2O: Measurement of the absolute values of the quadrupole and dipole contributions to the intensity of a pre-edge transition")
Authors
Robert D. Peacock, Tommaso Prosperi, Brian Stewart,