Article ID Journal Published Year Pages File Type
5389489 Chemical Physics Letters 2007 6 Pages PDF
Abstract
The transient structure of the ferrioxalate redox reaction intermediates have been measured by means of time resolved EXAFS and confirmed by DFT and H-F calculations. These data coupled with ultrafast optical studies suggest that the reaction mechanism involves dissociation before electron transfer occurs.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Electron transfer and dissociation mechanism of ferrioxalate: A time resolved optical and EXAFS study
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