| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5389490 | Chemical Physics Letters | 2007 | 5 Pages |
Abstract
Configurations of harmonic and anharmonic charge transfer vibronic excitons (CTVE-I and CTVE-II) in uranyl complexes. The co-existence of CTVE-I and CTVE-II provides a clear explanation to experimental results previously reported but not understood for Cs2UO2Cl4 and Cs2ZrCl6:UO2Cl42-. Hot bands with energy lower than zero-phonon lines are expected to be observed in the CTVE-I luminescence spectrum of uranyl ion in crystals. Doublet may appear in absorption spectrum when taking into account of tunneling between double wells in the excited state potential.
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Authors
G.K. Liu, V.S. Vikhnin,