Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5389654 | Chemical Physics Letters | 2006 | 6 Pages |
Abstract
The C2H6 and CO loss in the Ni+Â +Â acetone reaction leading respectively to Ni+(CO) and Ni+(C2H6) occurs through five elementary steps: encounter complexation, C-C activation, methyl migration, C-C coupling, and nonreactive dissociation, in which the third step is rate-determining. The alternative Ni+(CH3)2 yields is also possible.
Related Topics
Physical Sciences and Engineering
Chemistry
Physical and Theoretical Chemistry
Authors
Xiangfeng Chen, Wenyue Guo, Lianming Zhao, Qingtao Fu,