Article ID Journal Published Year Pages File Type
5389654 Chemical Physics Letters 2006 6 Pages PDF
Abstract
The C2H6 and CO loss in the Ni+ + acetone reaction leading respectively to Ni+(CO) and Ni+(C2H6) occurs through five elementary steps: encounter complexation, C-C activation, methyl migration, C-C coupling, and nonreactive dissociation, in which the third step is rate-determining. The alternative Ni+(CH3)2 yields is also possible.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
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