| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5389792 | Chemical Physics Letters | 2007 | 5 Pages |
Abstract
MP2/6-311++G(3df,3pd) calculations were performed on C2H3+ and C2H5+ three-center, two electron (3c-2e) systems with T-shaped approach of proton to acetylene and ethylene, respectively. H+â¯Ï interactions possess the characteristics typical for covalent bonds. Two complexes: C2H5+â¯C2H2 and C2H3+â¯H2 were also considered where C2H5+ and C2H3+ act as proton donating systems while C2H2 and H2 as proton acceptors, respectively - these complexes possess the characteristics of H-bonded species.
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Authors
SÅawomir J. Grabowski,