Article ID Journal Published Year Pages File Type
5389856 Chemical Physics Letters 2006 7 Pages PDF
Abstract
The tracer exchange of molecules between the phase adsorbed in nanoporous crystals and the surrounding gas phase is studied by molecular dynamics simulations. It is demonstrated that surface-limited adsorption is related to the potential energy difference between the inter- and intracrystalline space and may be observed also in the absence of structural surface defects.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
The influence of the desorption barrier on the transport of molecules through the external surface of nanoporous crystals
Authors
, , , , ,