Article ID Journal Published Year Pages File Type
5389899 Chemical Physics Letters 2006 5 Pages PDF
Abstract
Dimethyl ether is paired with hydroperoxy radical, and closed-shell analogues HOOH and OOH−. The more strongly bound minimum contains a OH⋯O bond, along with blueshifting CH⋯O; the other minimum contains exclusively CH⋯O. The data help explain how the H-bonds are affected by the open-shell character of the OOH radical.
Related Topics
Physical Sciences and Engineering Chemistry Physical and Theoretical Chemistry
Preview
Hydrogen bonding of radicals: Interaction of dimethyl ether with HOO, HOOH, and HOO−
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